Kraven the Hunter (Spider-Man The Animated Series)

Sergei Kravinoff was a skilled hunter in Africa, descended from Russian nobility. When hunting became prohibited Sergei became a guide. He met Mariah Crawford when she travelled to Africa to investigate after Dr. James Reeves went missing while researching in the jungle. Mariah and her team hired Sergei to guide them. Sergei acted as her bodyguard against the wild animals of the jungle, and he and Mariah fell in love.